RSP-2026-0001 · Materials SciencePublishedv2 · round 2

Defect-Tolerant Perovskite Thin Films for Stable Photovoltaics

Amy Winehaus, Dr. T. Stark, Prof. M. Curie · submitted May 8, 2026 · published Jul 5, 2026

  • perovskite
  • photovoltaics
  • thin films
  • stability
100% · Published

Open peer-reviewed research. Publication here is a review record, not an endorsement of clinical use — this material is not medical advice.

Abstract

We report a passivation strategy that suppresses non-radiative recombination at grain boundaries in metal-halide perovskite thin films, yielding devices that retain 92% of initial efficiency after 1,000 hours of continuous illumination. We characterize the mechanism with transient photoluminescence and space-charge-limited current measurements, and we release the full fabrication protocol and analysis pipeline openly.

Conflicts of interest
A.W. holds no patents on this chemistry. No industry funding.
Funding
National Materials Initiative grant NMI-2025-114.
Ethics / IRB
No human or animal subjects
License
CC-BY-4.0

Manuscript — v2

Viewer not loading? Open the PDF directly

Version history

  1. v2Jul 7, 2026PDF

    Added humidity-controlled aging (new Fig. 4), sensitivity analysis for excluded pixels, and 2025 references.

    Point-by-point response to reviewers

    Reviewer 1, boundary passivation: added XPS depth profiling (Fig. S6) confirming the interfacial layer. Reviewer 1, stats: sensitivity analysis added; conclusions unchanged. Reviewer 2, humidity: new 85%-RH aging series added as Fig. 4. Reviewer 2, citations: 2024–2025 replications now discussed in §4.

  2. v1Jul 7, 2026PDF

    Initial submission.

The Review Record

4 reviews on record

── Round 1 ──

Dr. Tony StarkMajor RevisionsMay 11, 2026
Summary
A genuinely promising stability result, but round-one evidence for the passivation mechanism was indirect. With direct interfacial characterization this becomes a strong paper.
Strengths
Clear hypothesis, pre-registered analysis, honest reporting of limitations, and openly available data and code. The figures are legible and the statistics report effect sizes.
Weaknesses
The sample is smaller than ideal for the secondary analyses, one control condition is missing, and two citations are outdated. Reproducibility of Figure 3 needs the raw pipeline.
Detailed comments
Methods: specify the randomization seed and hardware. Stats: add a sensitivity analysis for the excluded outliers. Figures: Fig. 3 needs error bars and an n per cell. Lit: engage the 2024–2025 replications. None of this is fatal; most is a revision away.
Review Record: RSR-2026-000001 — citable, permanent, on the reviewer's Crew Card.
Dr. Kurt CobainMinor RevisionsMay 11, 2026
Summary
Solid device work. My concerns are about aging conditions and statistical treatment of outlier pixels, both addressable.
Strengths
Clear hypothesis, pre-registered analysis, honest reporting of limitations, and openly available data and code. The figures are legible and the statistics report effect sizes.
Weaknesses
The sample is smaller than ideal for the secondary analyses, one control condition is missing, and two citations are outdated. Reproducibility of Figure 3 needs the raw pipeline.
Detailed comments
Methods: specify the randomization seed and hardware. Stats: add a sensitivity analysis for the excluded outliers. Figures: Fig. 3 needs error bars and an n per cell. Lit: engage the 2024–2025 replications. None of this is fatal; most is a revision away.
Review Record: RSR-2026-000002 — citable, permanent, on the reviewer's Crew Card.
★ Editorial decisionMajor RevisionsDr. Ozzy Iommi · Jul 7, 2026

Two careful reviews converge: the result is exciting but round-one mechanistic evidence was indirect. Please add direct interfacial characterization, a humidity-controlled aging series, and a sensitivity analysis for excluded pixels. We look forward to the revision.

── Round 2 ──

Dr. Tony StarkAcceptMay 14, 2026
Summary
The XPS depth profiling in the revision directly supports the interfacial-layer claim. My round-one concerns are fully resolved.
Strengths
Clear hypothesis, pre-registered analysis, honest reporting of limitations, and openly available data and code. The figures are legible and the statistics report effect sizes.
Weaknesses
Minor: Fig. S6 color scale could be colorblind-safe. Non-blocking.
Detailed comments
Methods: specify the randomization seed and hardware. Stats: add a sensitivity analysis for the excluded outliers. Figures: Fig. 3 needs error bars and an n per cell. Lit: engage the 2024–2025 replications. None of this is fatal; most is a revision away.
Review Record: RSR-2026-000003 — citable, permanent, on the reviewer's Crew Card.
Dr. Kurt CobainAcceptMay 14, 2026
Summary
The humidity series and sensitivity analysis close my concerns. Reproducible, honest, and openly licensed. Publish it.
Strengths
Clear hypothesis, pre-registered analysis, honest reporting of limitations, and openly available data and code. The figures are legible and the statistics report effect sizes.
Weaknesses
None blocking. Consider archiving the raw pipeline with a DOI.
Detailed comments
Methods: specify the randomization seed and hardware. Stats: add a sensitivity analysis for the excluded outliers. Figures: Fig. 3 needs error bars and an n per cell. Lit: engage the 2024–2025 replications. None of this is fatal; most is a revision away.
Review Record: RSR-2026-000004 — citable, permanent, on the reviewer's Crew Card.
★ Editorial decisionAcceptDr. Ozzy Iommi · Jul 7, 2026

Both reviewers confirm their concerns are resolved by the revision. This is exactly how open review should work — in public, on the record. Accepted, and eligible for The Amp given the commercial interest in stable perovskites. Congratulations.

Cite this paper

@article{RSP-2026-0001,
  title   = {Defect-Tolerant Perovskite Thin Films for Stable Photovoltaics},
  author  = {Amy Winehaus and Dr. T. Stark and Prof. M. Curie},
  year    = {2026},
  journal = {Review Slave},
  note    = {RSP-2026-0001. Openly peer reviewed; review record attached. License: CC-BY-4.0},
  url     = {https://thereviewslave.com/papers/cmrann196000diakcmqlni4h2}
}